Synthesis and X-ray Characterization of Organotelluroxane

Vikas Singh

Abstract


The reactions of diethyl tellurium (IV) diiodide [(C2H5)2TeI2 ] with conc. HNO3 afford
diorganotelluroxane. The X-ray crystal structures of organotelluroxane reveal the immediate
co-ordination geometry about the central tellurium atom to be pseudotrigonal
bipyramidal ( TBP) with one stereochemically active electron lone pair. The supramolecular
associations of the diorganotelluroxanes (IV) generated through Te---O secondary bonds.

Keywords


Organatelluroxane, Tellurite, x-ray crystallography

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DOI: https://doi.org/10.29320/sjnpgrj.v2i01.11030

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